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Session FP - Poster Session III.
POSTER session, Friday afternoon, May 17
Atrium, Chemistry Building
Pulsed proton-beam absorption spectroscopy, previously restricted to the infrared spectral region, has been extended to the visible and near infrared by the use of a silicon-avalanche photodiode (Si-APD) detector. The strongest absorption has been the c\,^3\Sigma _g^+\leftarrow a\,^3 \Sigma _u^+ with a number of different vibrational levels taking part in the liquid. Not nearly so many vibrational levels are observed for the gas transitions but rotational structure for the (0-0) transition has been well resolved. The signal-to-noise of the absorption spectrum in the liquid is markedly improved over that of previous workers, and a re-examination of the transition assignments will be presented.